ISSN: 2734-9438
Website: www.jomc.vn
Research on modifying of recycling polyol from waste polyurethane foam by vegetable oil for producing insulation materials
Abstract
Polyurethane (PU) foam is formed by the condensation of 2 components Polyol and Isocyanate. PU foam waste can be recycled by glycolysis which decomposes the polymer chains into polyol. The recycled polyol can then be used as the material to make new PU foam. However, the recycled Polyol is mixed with unprofitable primary and secondary amines, and it is not suitable for use as a raw material for the production of insulating foam because of its small average molecular weight, high hydroxyl index, etc. In this study, recycled Polyol will be modified with vegetable oil for the purpose of removing the amines mentioned above, creating the product with basic properties like commercial Polyol. Research results show that the regenerated Polyol after modification has the low hydroxyl index of 423.5 mg KOH/g and the viscosity of 4400 mPa.s, which are quite similar to that of commercial Polyol and the mass average molecular weight (2440.6) much higher than regenerated polyol.
References
- ,Se-Ra shin, Han-Na Kim, Dai-Soo Lee, "Sustainable rigid PU foams based on recycled polyols from chemical recycling of waste PU foams (DOI: 10.1002/app.47916)," Journal of Applied Polymer Science, 2019.
- ,Mir Mohammad Alavi Nikje, Amir Bagheri Garmarudi và Azani B.Idris, "PU waste reduction and recycling: from bench to pilot scales," Designed monomers and polymers 14 (P.395-421) ( https://doi.org/10.1163/138577211X587618), 2011.
- , Mir Mohammada Alavl Nikje (Smithers Rapra Technology Ltd), "Recycling of PU wastes," 2016.
- , Ron Zevenhoven (Helsinki University of Technology), "Treatment and disposal of polyurethane wastes: options for recovery and recycling," 2004.
- , Khalid Mahmood Zia, Hag Nawaz Bhatti, "Methods for PU and PU composites, recycling and recovery: A review," Reactive and Fuctional Polymers 67 (P.675 - 692), 2007.
- , D.Simon, A.M Borreguero, "Sustainable PU: Chemical recycling to get it (https://doi.org/10.1007/698_2014_275)," The Handbook of Environmental Chemistry (229-260), 2014.
- , Machado et al, "Process for modifying the glycolysis reaction product of polyurethane scrap (Patent number: US005300530A)," 1994.
- , Chao-Hsiung Wu et al, "Glycolysis of rigid polyurethane from waste refrigerators," Polymer degradation and stability 75, 2002.
- , Patrycja Jutrzenka Trzebiatowska et al, "Evaluation of the glycerolysis process and valorisation of recovered polyol in polyurethane synthesis," Reactive and functional polymers, 2019.
- A. S. "Introduction to mechanical recycling and chemical depolymerization (DOI: https://doi.org/10.1016/B978-0-323-51133-9.00004-8)," Recycling of polyurethane foams, 2018.
- H. S. A. G. "Latest development for recycling of PU foam out of end-of-life mattresses into polyol for rigid PU foam application".
- , Michał Sołtysiński, Kazimierz Piszczek and et al, "Conversion of polyurethane technological foam waste and post-consumer polyurethane mattresses into polyols – industrial applications (DOI: dx.doi.org/10.14314/polimery.2018.3.8)".Polimery 2018,63.
- , George P. Speranza et al, "Modification of polyols with epoxy resins," United States Patent - US 4316991, 1982.
- P. S. "Epoxxy-modified polyols and polymer-polyols useful in the preparation of improved plastics, including polyurethane foams, elastomers and the like," United States Patent (US 4495341), 1985.
- G. P. S. e. a. "Modification of polyols with epoxy resins for use in flexible polyurethane foams," United States Patent - US 4373034, 1983.
- G. P. S. e. a. "Polyisocyanurate from diols modified with epoxy resins (United States Patent US 4323658)," 1982.
- , Tayde Saurabh et al, "Epoxidation of vegetable oils: A review," International Journal of Advanced Engineering Technology Vol. II, 2011.
- , Padmasiri K.Gamage et al, "Epoxidation of some vegatable oils and their hydrolysed products with peroxyformic acid-optimised to industrial scale," J.Natn.Sci.Foundation Sri Lanka 2009 37 (4), 2009.
- M. Y. A. "Synthesis and properties of cross-linked polymers from epoxidized rubber seed oil and triethylenetetramine," Journal of applied polymer science, 2015.
- G. "Castor oil modified by epoxidation, transesterificationg and acrylation process: spectroscopic characteristics," International journal of polymer analysis and characterization (http://dx.doi.org/10.1080/1023666X.2017.1334171), 2017.
- , S. Meadows et al, "Studies on the synthesis and characterizaion of epoxidized soybean oil," ( https://www.researchgate.net/publication/320173456), 2016.
- P. "Effects of diferent epoxidation methods of soybean oil on the charateristics of acrylated epoxidized soybean oil-co-poly(methyl methaacrylate) copolymer," express polymer letters vol.7, No.11 (DOI: 10.3144/expresspolymlett.2013.89), 2013.
- E. d. R. N. ""New polyurethanes from vegetable oil-based polyol" (PhD Thesis)," 2011.
- P. v. V. M. N. "Chuyên đề "Nghiên cứu quá trình hóa lỏng xốp PU phế thải bằng phản ứng glycol phân tại Việt Nam"," Đề tài "Nghiên cứu tái chế polyurethane phế thải làm nguyên liệu để chế tạo vật liệu cách nhiệt", 2020.
- N. Y. P. C. "Epoxidized soybean oil (ESO-132) - Specification sheet".
- P. e. a. "Glycolysis recycling of rigid waste polyurethane foam from refrigerators," Environmental Technology 2014-Vol 35, No. 21, 2014.
- , Dai Soo Lee et al, "Báo cáo nhóm về kết quả biến tính polyol tái sinh từ xốp PU phế thải của Việt Nam, sử dụng dầu nành epoxy hóa (báo cáo nội bộ)," 2019.