ISSN:
Website: www.jomc.vn
Study on the fire-fighting capability and toxicity testing of fire-extinguishing powder in a combination of monoamonium photphate and inorganic salt
Abstract
Monoammonium phosphate has been known as the main material in production of fire extinguishing powder thanks to its outstanding firefighting ability and low toxicity. By mixing with some inorganic salts, a fire extinguishing powder includes monoammonium phosphate, inorganic phosphate compounds, inorganic sulfate compounds, magnesium hydroxide, inorganic carbonate compounds and other auxiliary additives has been synthesized. Properties of this fire extinguishing powder were evaluated such as thermal decomposition, fire extinguishing ability and biological toxicity in this study by using thermogravimetric analysis (TGA), fire testing and acute toxicity assessment (LD50)... The results showed that, on a laboratory scale, the fire was extinguished within 10 seconds after powder spray and did not reignite with a "virtually non-toxic" level of biological toxicity according to the OECD classification with the LD50 result reaching safe toxicity level
References
- TCVN 4878:2009 (ISO 3941:2007) phòng cháy chữa cháy – Phân loại đám cháy
- A.V. Kunin, S.A. Smirnov, D.N. Lapshin, A.D. Semenov, A.P. Il’in, Technology development for the production of ABCE fire extinguishing dry powders, Russian Journal of General Chemistry, 2016, Vol. 86, No. 2, pp. 450–459.
- Makarov, V.E. and Gorokhov, V.M., in Sb. Trudov “Goryuchest’ veshchestv I khimicheskie sredstva pozharotusheniya” (Coll. Of Works “Flammability of Substances and Chemical Extinguishing Agents”), Moscow: Vseross. Nauchno-Issled. Inst. Protivopozh. Obor., 1979, issue 6, pp. 139-141.
- USSR Inventor’s Certificate no. 829119, 1981
- USSR Inventor’s Certificate no. 596251, 1978
- Baratov, A.N., Zh. Vses. Khim. O-va. Im. D.I. Mendeleeva, 1974, vol. 19, p.531.
- Trevan JW. The error of determination of toxicity. Proc R Soc Lond. 1927; B.101: 483–514.
- Gad SC. Rodents model for toxicity testing and biomarkers. In: Gupta RC, editor. Biomarkers in toxicology. Academic Press; 2014. p. 7–69.
- Agrawal SP, Saxena VL. Prediction of LD50 of some common pesticides through QSAR (an alternative method to save experimental animals). Int J Pharm Sci Res. 2014; 5(12): 5356–5373. doi: 10.13040/IJPSR.0975-8232.5 (12).5356-73
- Badanthadka M, Mehendale HM. Hexachlorocyclopentadiene. In:
- Wexler P, editor. Encyclopedia of Toxicology. 33rd ed. Academic Press; 2014. p. 877–881.
- Fuentes D, Ray SD, Holstege CP. Anxiolytics, In: Wexler P, editor. Encyclopedia of Toxicology. 3rd ed. Academic Press; 2014. p. 280–286.
- Erhirhie EO, Ihekwereme, CP, Ilodigwe EE. Advances in acute toxicity testing: strengths, weaknesses and regulatory acceptance. Interdiscip Toxicol. 2018; 11: 5–12.
- Tiêu chuẩn quốc gia TCVN 6102:2020 (ISO 7202:2018) về Phòng cháy chữa cháy - Chất chữa cháy - Bột.
- Lê Phúc Chiến, Nguyễn Thị Thanh Tâm, Nguyễn Nguyên Bảo, Trần Phi Hoàng, Hồ Thái Như Quỳnh, Trần Cẩm Tú, Nguyễn Thị Như Quỳnh. Tạp chí Khoa học Công nghệ và Thực phẩm 20 (1) (2020) 68-75
- Đỗ Trung Đàm - Phương pháp xác định độc tính của thuốc, NXB Y học, Hà Nội (2014).
- J. CRAIG VOELKERT, A brief guide to fire chemistry and extinguishment theory for fire equipment service technicians (2009)

