ISSN:
Website: www.jomc.vn
Fabrication and evaluation of the characteristics of ion exchange membranes based on Nafion membranes
Abstract
This experiment has fabricated and evaluated the properties of ion exchange membranes based on Nafion membranes (hybrid membranes). The characteristic properties of the hybrid membrane were investigated such as: FT-IR spectroscopy, NMR spectroscopy, Thermogravimetric analysis (TG-DTG), scanning electron microscopy (SEM), ion exchange capacity (IEC), water absorption (WU) and ionic conductivity (σ). The survey results confirm the successful hybridization of NaSS and METAC into Nafion molecules. Changes in surface morphology of the hybrid Nafion membrane compared with the very smooth surface of the original commercial Nafion membrane (N212). Physicochemical properties such as ion exchange capacity (IEC), water absorption (WU) were shown to be reduced when the amount of NaPSS in the hybrid membrane was reduced. Ionic conductivity (σ) gives the ion transport capacity of the membrane will be changed when adjusting the monomer content in these membrane.
References
- Skyllas-Kazacos M, Rychcik M, Robins RG, Fane AG, Green MA (1986) New all-vanadium redox flow cell. J Electrochem Soc 133(5):1057-1058.
- Teng X, Yu C, Wu X, Dong Y, Gao P, Hu H, Zhu Y, Dai J (2018) PTFE/SPEEK/PDDA/PSS composite membrane for vanadium redox flow battery application. J Mater Sci 53(7):5204-5215.
- Wei X, Liu S, Wang J, He Z, Zhao K, Yang Y, Liu B, Huang R, He Z (2020) Boosting the performance of positive electrolyte for VRFB by employing zwitterion molecule containing sulfonic and pyridine groups as the additive. Ionics 26:3147-3159.
- Zheng L, Wang H, Niu R, Zhang Y, Shi H (2018) Sulfonated poly(ether ether ketone)/sulfonated graphene oxide hybrid membrane for vanadium redox flow battery. Electrochim Acta 282:437-447.
- Shi Y, Eze C, Xiong B, He W, Zhang H, Lim TM, Ukil A, Zhao J (2019) Recent development of membrane for vanadium redox flow battery applications: a review. Appl Energ 238:202-224.
- Ye J, Yuan D, Ding M, Long Y, Long T, Sun L, Jia C (2021) A cost-effective Nafion/lignin composite membrane with low vanadium ion permeation for high performance vanadium redox flow battery. J Power Sources 482:229023.
- Lu W, Shi D, Zhang H, Li X (2021) Advanced poly(vinyl pyrrolidone) decorated chlorinated polyvinyl chloride membrane with low area resistance for vanadium flow battery. J Membrane Sci 620:118947.
- Zhou X, Xue R, Zhong Y, Zhang Y, Jiang F (2020) Asymmetric porous membranes with ultra-high ion selectivity for vanadium redox flow batteries. J Membrane Sci 595:117614.
- Li A, Wang G, Quan Y, Wei X, Li F, Zhang M, Ur RI, Zhang J, Chen J, Wang R (2020) Sulfonated poly(ether ether ketone)/polyimide acid-base hybrid membranes for vanadium redox flow battery applications. Ionics 26(5):2467-2475.
- D. Chen, S. Kim, L. Li, G. Yang, M.A. Hickner RSC Adv., 2 (2012), pp. 8087-8094.
- D. Chen, M.A. Hickner, S. Wang, J. Pan, M. Xiao, Y. Meng J. Membr. Sci., 415-416 (2012), pp. 139-144.
- Peng K, Lai J, Liu Y (2017) Preparation of poly(styrenesulfonic acid) grafted Nafion with a Nafion-initiated atom transfer radical polymerization for proton exchange membranes. RSC Adv 7(59):37255-37260.
- Feng K, Liu L, Tang BB, Li NW, Wu PY (2016) Nafion-initiated ATRP of 1-vinylimidazole for preparation of proton exchange membranes. ACS Appl Mater Inter 8(18):11516-11525.
- Peng K, Wang K, Hsu K, Liu Y (2015) Atom transfer radical addition/polymerization of perfluorosulfonic acid polymer with the C–F bonds as reactive sites. ACS Macro Lett 4(2):197–201.
- S. Kim, J. Yan, B. Schwenzer, J. Zhang, L. Li, J. Liu, G. Yang, M.A. Hickner Electrochem. Commun., 12 (2010), pp. 1650-1653.
- D. Chen, S. Wang, M. Xiao, Y. Meng Energy Convers. Manage., 51 (2010), pp. 2816-2824.
- S. Xue, G. Yin Polymer, 47 (2006), pp. 5044-5049.
- H. Jung, J. Park Int. J. Hydrogen Energy, 34 (2009), pp. 3915-3921.
- K.A. Sung, W. Kim, K. Oh, M. Choo, K. Nam, J. Park, J. Power Sourc., 196 (2011), pp. 2483-2489.

